1st Edition

Chemical Thermodynamics and Information Theory with Applications

By Daniel J. Graham Copyright 2011
240 Pages 115 B/W Illustrations
by CRC Press

240 Pages 115 B/W Illustrations
by CRC Press

240 Pages
by CRC Press

Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications drawn from the intersection of thermodynamics... Read more

A Qualitative Look at Information
The Net of Information
Sources and Further Reading

A Quantitative Look at Information
Essential Ingredients
The Interface of Information with State Likelihood
The Role of Probability
Information and Expectation
Connecting Probability, Information, and Physical Properties
Probability Distribution Tools

Thermodynamic Infrastructure, States, and Fluctuations
Infrastructure
Equations of State
Systems and State Point Information

Thermodynamic Transformations and Information
Equilibrium States, Pathways, and Measurements
A Primer on Reversible Transformations
Reversible Transformations and Information
The Information Properties of Reversible Pathways

State Transformations and Information Economy
Different Thermodynamic Pathways with Identical Endpoints
Pathway Programming and Economy
Properties of Pathway Length and Information Economy

Thermodynamic Information and Molecules
Information at the Microscopic Scale
Molecular Message Tapes: Technical Considerations
Characteristics of Information at the Molecular Level

Thermodynamic Information and Chemical Reactions
Overview of Chemical Reactions
Chemical Reactions and Information
Reactions, Information, and Molecular Structure

Chemical Thermodynamics, Information, and Horizons
Horizons
Appendix A: Source Program for Constructing Molecular Message
Tapes and Computing Information
Appendix B: Answers to Selected Exercises
Index

Biography

Daniel J. Graham is with the Department of Chemistry at Loyola University in Chicago.