Among the materials found in nature’s many diverse living organisms or produced by human industry, those made from polymers are dominant. In nature they are not only dominant, but they are, as well, uniquely necessary to life. Conformations: Connecting the Chemical Structures and Material Behaviors of Polymers explores how the detailed chemical structures of polymers can be characterized, how their microstructural dependent conformational preferences can be evaluated, and how these conformational preferences can be connected to the behaviors and properties of their materials.
The authors examine the connections between the microstructures of polymers and the rich variety of physical properties they evidence. Detailed polymer architectures, including the molecular bonding and geometries of backbone and side-chain groups, monomer stereo- and regio-sequences, comonomer sequences, and branching, are explicitly considered in the analysis of the conformational characteristics of polymers.
This valuable reference provides practicing materials engineers as well as polymer and materials science students a means of understanding the differences in behaviors and properties of materials made from chemically distinct polymers. This knowledge can assist the reader design polymers with chemical structures that lead to their desired material behaviors and properties.
Polymer Physics. Polymer Chemistry. Determining the microstructural dependent conformational preferences of polymer chains. Experimental determination of polymer microstructures with 13C-NMR spectroscopy. Connecting the behaviors/properties of polymer solutions and liquids to the conformational preferences established by their microstructures. Connecting the behaviors/properties of polymer solids to the conformational preferences established by their microstructures. Comparison of the behaviors of man-made synthetic polymers and their materials to those polymers and materials produced in nature.