1st Edition

Mannich Bases-Chemistry and Uses



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ISBN 9780849344305
Published September 16, 1994 by CRC Press
304 Pages

USD $450.00

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Book Description

This book covers the remarkable development of the chemistry and applications of Mannich bases within the last 30 years. It provides an updated and comprehensive look at these compounds-compounds identified at the beginning of the century. Particular emphasis is placed on the versatile chemistry of Mannich bases.
Synthesis and reactions of Mannich bases are systematically treated in the first two chapters, which include a thorough review of the most recent advances on the topic. Chapters 3 and 4 are devoted to the macromolecular chemistry and the chemistry of natural compounds, two emerging areas of application of the chemistry of Mannich bases. Chapter 5 deals with structure/property relationships that enable the production of tailor-made molecular structures suited to different practical applications. A survey of the main uses of individual Mannich bases according to the type of industrial branch is also reported.

Table of Contents

Introduction
Synthesis of Mannich Bases
Aminomethylation Reactants
Aminomethylation Reaction
Synthesis and Chemical Structure of Mannich Bases
Survey of Substrates Subjected to Mannich Reaction
Reactions of Mannich Bases
Cleavage
Amino Group Replacement
Reduction
Addition of Organometals
Cyclization
Miscellaneous Reactions
References to Introduction and Chapters I and Ii
Mannich Bases In Macromolecular Chemistry
Mannich Polymerization
Polymerizations Involving Mannich Bases
Crosslinked Products from Mannich Bases
Functionalization of Macromolecular Compounds
References to Chapter III
Mannich Bases in the Chemistry of Natural Products
Alkaloids
Steroid Hormones
Natural Macromolecules and Related Compounds
Pharmacologically Active Substances and Vitamins
Miscellaneous Compounds
References to Chapter IV
Practical Applications of Mannich Bases
Structure/Property Relationships in Mannich Bases and Derivatives
Industrial Branches Employing Mannich Bases and Derivatives
References to Chapter V

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