1st Edition

Molecular Basis of Chromatographic Separation



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ISBN 9780849376962
Published July 3, 1997 by CRC Press
256 Pages

USD $350.00

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Book Description

Chromatographic separation is widely used in many scientific disciplines today, having an ever increasing number of scientific and technological applications. The widespread use of this rapid and powerful technique requires that it be fully understood, so that the most suitable may be determined for each possible separation problem in each possible domain of scientific research and technology. Molecular Basis of Chromatographic Separation provides complete coverage of the practical and molecular aspects of this popular technique. It compiles and evaluates recent results, outlines available methods, and discusses how to select the best method for a particular application.

Table of Contents

Adsorption Phenomena and Molecular Interactions in Chromatography
Adsorption Phenomena in Gas-Liquid Chromatography
Adsorption Phenomena in Liquid Chromatography
Competitive Adsorption of the Eluent Components
Competitive Adsorption of Analytes
Molecular Forces in Chromatography
Gas Chromatography
Fundamentals
Models of GLC Retention and Separation
Influence of Adsorption Side Effects on Retention Behavior
Descriptors of GLC Retention and Their Correlation with Molecular Parameters
Retention Time
Capacity Factor
The Kováts Index
The Takács Retention Index
Other Descriptors
Application of Solute Parameters Retention Relationships
Liquid Chromatography
Thin-Layer Chromatography
Principles of Adsorption and Reversed-Phase Thin-Layer Chromatography
Molecular Basis of Separation in Adsorption Thin-Layer Chromatography
Molecular Basis of Separation in Reversed-Phase Thin-Layer Chromatography
High-Performance Liquid Chromatography
Fundamentals
Direct (Normal) Phase High-Performance Liquid Chromatography
Reversed-Phase Chromatography
Graphitized Carbon Packing Materials
Other Metal-Oxide Support
New Reversed-Phase Columns
Appendix
References
Index

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