1st Edition

Photoelectrochemical Solar Conversion Systems
Molecular and Electronic Aspects

ISBN 9780367380687
Published October 23, 2019 by CRC Press
356 Pages

USD $74.95

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Book Description

Providing new insights into the molecular and electronic processes involved in the conversion of sunlight into chemical products, Photoelectrochemical Solar Conversion Systems: Molecular and Electronic Aspects begins with an historical overview and a survey of recent developments in the electrochemistry of semiconductors and spectroscopic techniques. It then provides a comprehensive introduction to the science of conversion cells, reviews current issues and potential directions, and covers a wide range of materials from organic to inorganic cells.

Employing a tutorial organization with balanced coverage of electrochemistry and solar energy conversion, this book covers:

  • The conversion of sunlight into chemical energy and different actual conversion concepts

  • Electrochemical methods for the construction and characterization of electrolyte-metal-oxide-semiconductor contacts (EMOS) in the nanodimensions, the so-called nano-emitter concept, including the electrochemical formation of metal clusters of catalytic metals and the formation of passivating layers by anodization

  • The fundamentals of electrocatalysis with emphasis on the hydrogen evolution reaction and the electrochemical CO2 reduction

  • Classical and quantum mechanical theories of electron transfer reactions in metal-electrolyte interfaces and their relation with surface electronics

  • The physicochemical characterization of the model system Si-SiOx-metal-electrolyte by means of modern electrochemical, surface, and spectroscopic methods

  • Improvements of conversion efficiency by means of optical effects, for example, the generation of surface plasmons by nano-dimensioned arrangements of optically active metals

Table of Contents

Principles and Systems in Light-Induced Energy Conversion. Nano-Dimensioned Systems Based on Semiconductor-Oxide- Metal-Electrolyte Contacts. Physics of Electrolyte-Metal-Oxide-Semiconductor (EMOS) Contacts in Nano-Dimensions. Electrocatalysis on Nano-Dimensioned EMOS Contacts. Electronics and Chemistry of Electrolytes-Metal-Oxide- Semiconductor Contacts. Optical Effects: Current Approaches and Future Directions.

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Muñoz, Andrés G.