Radiation-Chemical Processes in Solid Phase: Theory and Application, 1st Edition (Hardback) book cover

Radiation-Chemical Processes in Solid Phase

Theory and Application, 1st Edition

By Evginiy I. Grigoriev, Leonid I. Trakhtenberg

CRC Press

240 pages

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Hardback: 9780849394362
pub: 1996-11-14
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Unlike many other references, Radiation-Chemical Processes in Solid Phase analyzes experimental data on radiolysis in terms of solid-state physics. It traces the effect exerted by media from primary processes of radiation-substance interaction to final products.

The authors consider the main chemically active elementary excitations arising under irradiation of solids and discuss the mechanisms of chemical reactions induced by them. They present the general principles of solid-state and molecular physics, and cover numerous radiation-chemical processes.

Table of Contents

General Ideas of the Solid State Theory and Molecule Physics

The Band Structure

The Phonon Spectrum

Surface Phenomena

Dissociation of Excited Molecules

Interaction of Radiation With a Solid

Absorption of Ionizing Radiation by a Solid

Short-Lived Chemically Active Elementary Excitations in a Solid

Spatial Nonuniformity of Absorbed Energy Distribution

Absorption of Energy in Heterogeneous Systems

Primary Chemical Processes in the Irradiated Solid

Ion Reactions

Reactions of Electron-Excited Particles

Radical Reactions

Processes with Participation of Stabilized Electrons

Low Temperature Radiation-Chemical Reactions

General Knowledge about the Peculiarities of Low-Temperature Reactions

Descriptive Methods of Low-Temperature Solid-Phase Reactions

Low-Temperature Radical Reactions Experimental Data

Modified Theory of Radiationless Transitions


Rate Constant of Solid Phase Chemical Reaction

Radical Reactions

Reactions with the Ion Transfer

Comparison of Theoretical and Experimental Data

Kinetic Peculiarities of Solid-Phase Radiation Chemical Reactions

Radicals Annihilation in the Process of Their Accumulation under Radiation

Kinetics of Radical Reactions

Compensation Effect and Cage Effect

Recombination Kinetics of Free Radicals in the Solid Phase

Photoradiation Processes

Dependence of the Radicals Concentration on the Way of Irradiation

Creation of the Radicals under the Absorption of Light by Molecules Excited with Radiation to the Lower Triplet State

Kinetics of the Radicals Creation under the Absorption of Light with the Stabilized Electrons

The Elementary Processes of Photochain Reactions

Heterogeneous Radiation-Chemical Processes

Radiation Effect on Surface Properties

Active Particle Reactions

Radiolysis of Substances in the Absorbed State

Applied Problems of Radiation Chemistry of Solids

Radiation Modification of Materials

Radiation-Chemical Problems of Nuclear and Radiation-Chemical Industry

Radiation Processing in Microelectronics

Biological and Medical Aspects of Radiation Processing


Subject Categories

BISAC Subject Codes/Headings:
SCIENCE / Chemistry / Inorganic
SCIENCE / Solid State Physics