The Anomeric Effect: 1st Edition (Hardback) book cover

The Anomeric Effect

1st Edition

By Eusebio Juaristi, Gabriel Cuevas

CRC Press

256 pages

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Hardback: 9780849389412
pub: 1994-10-12
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Description

This book provides a comprehensive review of the structural, conformational, and chemical manifestations of the anomeric effect. In order to present a cogent discussion of this most fundamental and relevant phenomenon, three chapters examine our present understanding of the origin of this conformational effect, based upon a wealth of theoretical and physical data. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect. The remainder of the book is devoted to new areas of development in the topic-such as differentiation of the endo and exo anomeric interactions, specific analysis of the enthalpic component of anomeric effects, critical evaluation of the kinetics and reverse anomeric effects, discovery of a new substantial effect in second- and lower-row anomeric segments, and others.

Table of Contents

Historical Aspects and Definitions

Origin and Consequences of the Anomeric Effect

Theoretical Studies of the Anomeric Effect

Stereoelectronic Effects Associated with the Anomeric Effect

Endo and Exo Anomeric Interactions

The Enthalpic Anomeric Effect

Second- and Lower-Row Anomeric Interactions

The Reverse Anomeric Effect

The Kinetic Anomeric Effect

Applications of the Anomeric Effect in Organic Synthesis

About the Series

New Directions in Organic & Biological Chemistry

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Subject Categories

BISAC Subject Codes/Headings:
MED071000
MEDICAL / Pharmacology
SCI013040
SCIENCE / Chemistry / Organic
SCI013060
SCIENCE / Chemistry / Industrial & Technical