1st Edition

Handbook of Aluminum Bonding Technology and Data

By J. D. Minford Copyright 1993

    A reference that offers comprehensive discussions on every important aspect of aluminum bonding for each level of manufacturing from mill finished to deoxidized, conversion coated, anodized, and painted surfaces and provides an extensive, up-to-date review of adhesion science, covering all significa

    Preface

    INTRODUCTION

    Basis of Strength Development and Joint Durability in Structural Aluminum Joints

    Adhesive Bonding and the Aluminum Aerospace Industry

    Adhesive Bonding Developments Outside the Aerospace Industry

    FACTORS AFFECTING ADHESION

    Introduction to Adhesion Theories

    Mechanical Interlocking Theory

    Diffusion Theory

    Electronic (Electrostatic) Theory

    Adsorption Theory

    Rheological (Viscoelastic) Theory

    Techniques for Measuring Adhesion

    Summary

    SURFACE CHARACTERISTICS OF ALUMINUM

    General Considerations

    Chemical and Physical Aspects of Adhesion Between Aluminum Surfaces and Adhesives

    Forms of Aluminum Oxide on the Adherend Surface

    Morphology of Regenerated Oxides

    Effect of Water-Rinsing Conditions After Deoxidation

    Conversion Oxides

    High-Temperature Thermal/Water Oxide Coatings

    Boehmite Oxide and Aluminum Joint Durability

    Surface Chemistry of Aluminum Affecting Bond Durability

    Interaction Between the Adhesive and Aluminum Oxide

    SURFACE TREATMENT OF ALUMINUM ADHERENDS

    Introduction

    Soil Removal-Only Procedures

    Soil Removal-Abrade-Reclean Procedures

    Soil Removal Plus Chemical Deoxidizing Procedures

    Primers as Part of the Pretreatment Procedure for Bonding

    Coupling Agents as Specialized Primers

    Prepainted Aluminum Surfaces as Primed Aluminum Adherends

    Specialized Treatments of Aluminum Foil

    Modification of Other Adherends for Subsequent Bonding to Aluminum Ill

    Addendum of Additional References

    SELECTION OF AN ADHESIVE

    Theoretical Considerations

    Adhesive Materials and Properties

    Natural and Synthetic Elastomers in Adhesives

    Thermoplastic Resin Adhesives

    Thermosetting Resin Adhesives

    Sealant Formulations

    Thermally or Electrically Conductive Adhesives

    Primers for Adhesive-Bonded Aluminum Joints

    Film Versus Tape Adhesive Considerations

    Fire- and Flame-Resistant Adhesives and Sealants

    Microbial Contamination of Adhesives

    DESIGN OF ALUMINUM-BONDED JOINTS

    Introduction

    Stress Factors

    Geometry Factors

    More Complicated Joint Designs

    Final Design Guidelines

    MECHANISMS OF BOND JOINT FAILURE

    Introduction

    Polymer Surface Degradation and Polymer Stability

    Elastic and Viscoelastic Adhesion Considerations

    Interaction of Aluminum Surface with Polymers

    Mechanics Analysis

    Fracture Mechanics of Adhesive Joints

    Flexible Joint Studies

    Rigid Joint Studies

    Effect of Joint Geometry

    Peel Joint Considerations

    Comparison of Different Joint Designs

    Testing Temperatures and Rate Considerations

    Other Bondline Characteristics Affecting Joint Failure

    WATER IN THE SERVICE ENVIRONMENT

    Introduction

    Mechanisms of Failure

    The Adhesive Pathway

    Effects of Water on the Interface

    Aluminum Adherend Stability Considerations

    TEST EVALUATION STANDARDS

    Industry Specifications and Standards

    Government Standards

    Additional General Information Sources

    General Development of Testing Procedures

    Testing of Adhesive Formulations

    Testing the Properties of Joints

    Nondestructive Testing Procedures (NDT Techniques)

    Joint Strength Retention Procedures

    Some Criticisms of Standard ASTM Testing Methods

    DURABILITY OR PERMANENCE OF ALUMINUM-BONDED JOINTS

    Introduction

    Models Bearing on Adhesive Joint Performance

    Aluminum Adherend Surface Conditions that Affect Durability

    Failure Site Variabilities

    Adhesive Factors Affecting Durability

    Adherend Effects on Joint Durability

    Effect of Adhesive Choice on Joint Durability

    Joint Permanence as a Function of Surface Pretreatment

    Predictability of Long-Term Joint Permanence Results in Natural Atmospheric Weathering Based on Short-Term Accelerated-Weathering Testing

    Protective Coatings for Extending the Durability of Aluminum Joints

    Effect of Primers on Aluminum Joint Permanence

    Effect of Silanes on Aluminum Joint Permanence

    Bond Permanence with Simultaneous Stress and Weathering

    Bond Permanence of Combination Adhesive and Resistance Spot-Welded Joints (Weldbond)

    Bond Permanence of Combination Adhesive and Rivet or Metal Clinching Joints (Rivbonds and Clinchbonds)

    Bond Permanence with Contaminated Aluminum Surface Joints

    Permanence of Bondments Involving Aluminum Cast Alloy Adherends

    Bond Permanence of Aluminum-to-Plastic Adherend Joints

    Bond Permanence of Aluminum-to-Wood Joints

    Formulation of Oil-Accommodating Adhesives

    Miscellaneous Technical Reports

    APPLICATIONS OF ADHESIVES IN BONDING ALUMINUM STRUCTURES

    Introduction

    Adhesive Curing and Manufacturing Situations

    Aerospace Application Bonding of Aluminum

    Sandwich Panels and Laminates

    Automotive, Truck, and Trailer Applications

    Electric and Electronic Applications for Adhesives and Sealants

    Construction Industries

    Packaging Applications

    Appliance Applications

    Medical Applications

    Sporting Goods Applications

    Miscellaneous Applications and General Information Reports Relative to Use of Adhesives in Manufacturing from Adhesives Age Magazine

    References

    Author Index

    Subject Index

    Biography

    J. D. Minford

    ". . .A must book for anyone involved in adhesives technology. "
    ---Materials and Manufacturing Processes