This monograph summarizes scientific achievements in the field of polysaccharide chemistry performed in the last decade. For the first time, the particular features of polysaccharide structure, physical-chemical properties and biochemical transformations in their interrelations are considered as well as the questions of polysaccharide modification along the whole hierarchical chain, including starch mono-, di-, oligo- and polysaccharides, chitin, chitozan and cellulose. Polysaccharide interactions with diverse solvents and low-molecular, macrocyclic and high-molecular substances in solutions are scrutinized. Several aspects of mechanical-chemical modification of polysaccharides in solid state and in gel are observed. Modern concepts of enzyme degradation of polysaccharides and technologies of natural polymers processing are analyzed. The book is intended for wide range of readers: students, post graduates, engineers and scientists engaged in polymer chemistry, organic and physical chemistry.
PREFACE
G.E.Zaikov
THE ROLE OF POLYSACCHARIDES AND CELLULOSE FOR MODERN SCIENCE AND TECHNOLOGY
A.G. Zakharov
MOLECULAR COMPLEXES OF MONO- AND OLIGOSACCHARIDES IN SOLUTIONS
E.V. Parphenyuk, .. Davydova
Introduction
Particularities of structure and state of mono- and oligo-saccharides in solutions
Tautomeric equilibriums and conformations in solution
Stereochemistry of mono- and oligosaccharides. Its influence on aquation and reactivity
Molecular complexes of mono- and oligosaccharides with macro-cycle compounds in solutions
Cyclodextrines
Cyclophanes
Kraunethers
Characteristic ofinteractions saccharide-ether in solutions from the point of view of virial enthalov coefflcients ofpaired interactions
Thermodvnamic parameters of molecular associates formation between some saccharides and kraunethers in water
Bulk effects ofinteractions in ternary svstems saccharide-ether-il!ater
Interactions of mono- and oligosaccharides with small molecules presenting biological interest
Interactions of mono- and oligosaccharides with nitrogen-containing molecules in solutions
Interaction of mono- and oligosaccharides with aminoacids and peptides in water solutions
References
CYCLODEXTRINS. PHYSICAL-CHEMICAL ASPECTS OF FORMATION OF COMPLEXES "HOST -GUEST" AND MOLECULAR SELECTIVITY IN RELATION TO BIOLOGICALLY ACTIVE COMPOUNDS
I.V. Terekhova, O.V. Kulikov
Introduction
Structure and physical-chemical properties of cyclodextrins
Complexation properties of cyclodextrins and the main directions of their practical use
Thermodynamic and structural aspects of selective interactions of cyclodextrins with some biologically active molecules in water solution
Approaches used for thermodynamic formulation of intermolecular interactions
Complexation of a- and {:J-cyclodextrines with bases of nucleic acids. Thermodynamic and H NMR-spectroscopic investigatons.
Thermodynamics and mechanism of formation of supramolecular complexes of nature and modified cyclodextrines with some vitamins
References
INCLUSION COMPLEXES OF AMYLOSE
A.V. Agafonov
Introduction
Structural and permolecular organization of amylose molecules in solid phase and solutions
Structural particularities of amylose molecules
The structure of inclusion compounds of amylose
Crystal inclusion complex iodine-amylose
The structure of amylose solutions
Amylose complexation with small molecules in solutions
Formation of inclusion complexes iodine-amylose in solutions
Complexation of amylose inclusion compounds with dyes in solutions
Catalytic effect of inclusion complexes
References
PHYSICAL-CHEMICAL PROPERTIES OF SOLUTIONS OF NATURE POLYMERS AND THEIR MIXTURES
E.S. Sashina, N.P. Novoselov
Introduction
Physico-chemistry of cellulose solutions and its mixtures with nature and synthetic polymers in solutions and films
Cellulose dissolving in N-methylmorpholine-N-oxide and binary systems on its base
Compatibility of cellulose with nature and synthetic polymers in solutions and films
Physical chemistry of fibroin solutions and its compatibility with nature and synthetic polymers in solutions and films
Physical-chemical properties of fibroin solutions
Investigation of fibroin compatibility with nature and synthetic polymers in solutions and films
References
REGULARITIES OF STRUCTURE FORMATION DURING PROCESSING OF CELLULOSE AND ITS DERIVATIVES IN THE PRESENCE OF LIQUIDS
A.G. Zakharov, A.N. Prusov
Introduction
Modern conceptions of cellulose structure
Physical and physical-chemical basis of cellulose activation
Solvation processes and structure formation in liquid-phase ether cellulose solutions
References
INTERACTION OF CELLULOSE AND OTHER POLYSACCHARIDES WITH WATER SYSTEMS
E.L.Akim
Introduction
The influence of water and water systems on relaxation state of cellolose and other polysaccharides
Relaxation (physical) state of cellulose
The influence of plasticizing mediums on relaxation (physical) state of polymer
The influence of water and other low-molecular liquids on relaxation state of cellulose
On the mechanism of devitrijication of cellulose under the water and other low-molecular liquids action
Specific particularities of chemical, physical-chemical and mechanochemical processes at hyperelastic cellulose state
The role of cellulose hyperelastic state under realization of its chemical transformations
The change of relaxation state of cellulose and some other polysaccharides under production and processing of paper and cardboard
The influence of drying on relaxation state of wood's polymer components
Change of cellulose, hemicellulose and lignine relaxation state under paper production
The influence of cellulose, hemicellulose and lignine on strength of paper sheet under the use of various fiber half-finished products
Multi-component cellulose suspensions
The role of polymer relaxation state in processes of cellulose compositional materials production
The role of capillary-porous structure of paper under its plating
References
MECHANOINITIATED STRUCTURAL AND CHEMICAL TRANSFORMATIONS IN SOLUTIONS AND LIQUID DISPERSIONS OF POLYSACCHARIDES
I.M. Lipatova, A.P. Moryganov
Introduction
Ultrasonic and hydroacoustic apparatus
Mechanodestruction of polysaccharides in solutions and gels
Mechanodestruction of dissolved polysaccharides initiated by ultrasonic and shearing effects
Mechanodestruction gelatinized starch under hydroacoustic effects
Mechanoinitiating structure processes in polysaccharides solutions and gels
The influence of hydroacoustic effects on rheologic properties of Nacarboxymethylcellulose
Structural transformations in starch hydrogels initiated by hydroacoustic effects
The influence of intensive mechanical effects on starch reaction ability
The influence of hydroacoustic effects on the rate of reaction of starch heterogeneous oxidation
The influence of hydroacoustic effects on reaction rate of gelatinized starch oxidation
The influence of ultrasonic and hydroacoustic effects on the rate of acid hydrolysis of gelatinized starch
The examples of industrial application of rotor-impulse apparatus in technologies of speed production of modified starch materials
References
NATURE POLYSACCHARIDES. OXIDATIVE REACTIONS OF CHITOSAN
K.Yu. Murinov, N.N. Kabal'nova, I.R. Mullagaliev, Yu.B. Monakov
Introduction
Chitosan oxidation by ozone
Chitosan oxidation by ozone in heterogeneous medium
Chitosan oxidation in homogeneous medium
Oxidation of chitosan by hydrogen peroxide
Oxidation of chitosan by hydrogen peroxide in heterogeneous medium
Oxidation of chitosan by hydrogen peroxide in homogeneous medium
Chemiluminescence under chitosan interaction with hydrogen peroxide
Chitosan oxidation by oxygen-containing chlorine compounds
Chitosan oxidation by sodium hypochlorite
Chitosan oxidation by sodium chlorite
Chitosan oxidation by sodium chlorite under the addition of catalytic amounts of sodium hypochlorite and nitroxyl radicals (,,,- tetramethyl--phenyl--imidazolin-oxide--oxyl)
Chemiluminescence under chitosan oxidation by sodium chlorite and hypochlorite
Kinetic regularities of chitosan oxidation by chlorine dioxide
Rheologic properties of chitosan solutions
Investigation of chitosan oxidative destruction initiated by sodium chlorite and hydrogen peroxide by rheology method
Investigation of chitosan sorption properties and its modified derivative
References
Biography
Zaikov\, Gennady
