1st Edition

Advances in Chromatography Volume 35

Edited By Phyllis R. Brown, Eli Grushka Copyright 1995
448 Pages
by CRC Press

448 Pages
by CRC Press

"Volume 35 examines timely subjects such as performance requirements, detection modes, and ancillary techniques for optical detectors in capillary electrophoresis; and more."

Preface

Contributors to Volume 35

Contents of Other Volumes

Optical Detectors for Capillary Electrophoresis

Edward S. Yeung

Introduction

Performance Requirements

Various Detection Modes

Various Ancillary Techniques

Summary

References

Capillary electrophoresis Coupled with Mass Spectrometry

Kenneth B. Tomer, Leesa J. Deterding, and Carol E. Parker

Introduction

Instrumentation

Addressing limitations

Applications

Capillary electrophoresis Coupled with Tandem Mass Spectrometry

Conclusions

References

Approaches for the Optimization of Experimental Parameters in Capillary Zone Electrophoresis

Haleem J. Issaq, George M. Janini, King C. Chan, and Ziad El Rassi

Introduction

Basic Theoretical Concepts

Experimental Variables that Influence Separation Parameter

References

Crawling Out of the Chiral Pool: The Evolution of Pirkle-Type Chiral Stationary Phases

Christopher J. Welch

Introduction

Chirality and Chiral Pool

Production of Enantioenriched Compounds

Beyond the Chiral Pool

Evolution of Brush-type Chiral Stationary Phase Design

Conclusion

References

Pharmaceutical Analysis by Capillary Electrophoresis

Sam F. Y. Li, Choon Lan Ng, Chye Peng Ong

Introduction

Modes of Capillary Electrophoresis

Buffer modifiers

Applications

Comparison with High-Performance Liquid Chromatography

Conclusion

References

Chromatographic Characterization of Gasolines

Richard E. Pauls

Introduction

Compound Class Methods

PIONA Methods

Physical Properties

Benzene

Aromatics

Olefins

Oxygenates

Summary

References

Reversed-Phase Ion-Pair and Ion-Interaction Chromatography

M. C. Gennaro

Introduction

Retention Mechanism in Ion-Pair and Ion Interaction Chromatography

Dependence of Retention on Different Interpedent Factors

Experimental Conditions and Applications

Chemometric Optimization Methods

References

Error Sources in the Determination of Chromatographic Peak Size Ratios

Veronika R. Meyer

Introduction

General Remarks

Contamination Errors

Different Behavior of the Two Compounds

Interconversion of Compounds

Use of Peal Heights Without Calibration

Detector Nonlinearity

Integration Errors

Incomplete Resolution

Conclusions

References

Index

Biography

Phyllis R. Brown is Professor of Chemistry at the University of Rhode Island in Kingston, where she has taught since 1973. The author or coauthor of over 170 journal articles and several books, she edited the volume HPLC in Nucleic Acid Re­search. She also serves as an editorial board member for the Journal of Liquid Chromatography (both titles, Marcel Dekker, Inc.) and on the Advisory Board of Analytical Chemistry. Dr. Brown received the B.S. degree (1944) in chemistry from George Washington University, Washington, D.C., and the Ph.D. degree (1968) in chemistry from Brown University, Providence, Rhode Island.

Eli Grushka is Professor of Analytical Chemistry at the Hebrew University of Jeru­salem in Israel. He is the author or coauthor of over 130 scientific articles in the field of separation science. He is the editor or co-editor of several books, including New Developments in Separation Science and Preparative Scale Chromatography and he serves on the editorial boards of several journals, including Separation Science and Technology and Analytical Letters (all titles, Marcel Dekker, Inc.). Dr. Grushka received the B.S. degree (1963) from Long Island University, Brooklyn, New York, and the Ph.D. degree (1968) from Cornell University, Ithaca, New York.

"The overall quality of the chapters in this collected volume is quite high, and each chapter would be greatly beneficial to anyone needing a quick introduction into one of the areas covered. Any library maintaining the series should definitely acquire volume 35. "
---Journal of Pharmaceutical and Biomedical Analysis
". . .All of the reviews presented in this volume are not only pleasant to read but they offer a good survey of the latest achievements in the field. . .the editors should be congratulated for a well done job. For its price the volume is a good buy. "
---Journal of Chromatography A
"This volume will make an excellent addition to any analytical chemist's collection. "
---Journal of the American Chemical Society
". . .Another thoroughly recommended reference volume for the chromatographer. "
---Analyst