This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine containing monomers of diallyl and acrylic nature and their structure and investigation of their radical (co)polymerization and properties of new (co)polymers. The first parts of the book describe radical polymerization of these monomers and their co-polymerization with diallyldialkylammonium derivatives, features of their kinetic behavior in these processes (for example, polymerization rates, reactivity ratios) The sections on phycal chemical methods (IR, NMR, DSC ect.) are especially important for studying of structure and properties of synthesized monomer and polymer compounds. The book is finely illustrated with about hundred original figures, schemes and tables including kinetics, NMR, IR spectroscopy, biocide and other data.
Table of Contents
Preface List of Abbreviations Introduction Chapter 1. Synthesis of Guanidine Containing Monomers Synthesis of Diallyl Guanidine Containing Monomers Synthesis of Vinyl Guanidine Containing Monomers References Chapter 2. Radical Polymerization of Guanidine Containing Monomers Radical Polymerization of Diallyl Monomers Radical Polymerization of Vinyl Monomers References Chapter 3. Radical Copolymerization of Guanidine Containing Monomers with Diallyldimethylammonium Chloride Radical Copolymerization With participation of Acrylic Acids and Nitrogen Containing Diallyl Salts Radical Copolymerization of Diallyl Guanidine Monomers with Diallyldimethylammonium Chloride Radical Copolymerization of Guanidine Monomer Salts of Acrylic Acids with Diallyldimethylammonium Chloride in Water Mediums References Chapter 4. Investigation of Physical and Chemical Properties of Guanidine-Containing Monomers and (Co)Polymers Synthesized Compounds and their IR Spectroscopy Characteristics Investigation of Synthesized Monomer and Polymer Products by 1H NMR Spectroscopy Thermo-Physical Characteristics of Synthesized Products Chapter 5. Biocyde Activity of Polyelectrolytes Biocide Properties and Mechanism of Biocide Action of Polyelectrolytes Biocide and Toxicological Properties of Synthesized Novel Guanidine Containing Polymer Products References Conclusions Appendix
Nikolai A. Sivov, Ph.D. (1987) in Chemistry, Moscow State University, is Head of the Laboratory of the Institute of Petrochemical Synthesis RAS. He has published on synthesis of monomers, polyelectrolites and biocide polymers including structure and composition of (meth)acrylateguanidines, their homo- and copolymers.