Chemical Processes with Participation of Biological and Related Compounds : Biophysical and Chemical Aspects of Porphyrins, Pigments, Drugs, Biodegradable Polymers and Nanofibers book cover
1st Edition

Chemical Processes with Participation of Biological and Related Compounds
Biophysical and Chemical Aspects of Porphyrins, Pigments, Drugs, Biodegradable Polymers and Nanofibers




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ISBN 9789004162105
Published December 23, 2008 by CRC Press
422 Pages

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Book Description

The book is devoted to kinetics and thermodynamics of the processes with participation of some biological compounds and their synthetic analogues. Aspects of their acting as model enzymes, molecular receptors, photo sensitizers, pharmocophores, and biopharmaceutical compounds are under consideration. Quantitative characteristics of transfer of cations, anions and small organic molecules, fermentative catalysis, diffusion of the drug molecular through biological membranes are found. Mechanisms of the processes are discussed. Biological activity of studied compounds is evaluated. Bio-damages of materials as well as adhesions of microorganisms on materials surface are investigated.

Table of Contents

Preface
Foreword

Synthetic and Natural Bacteriochlorins: Synthesis, Properties and Applications M.A. Grin and A.F. Mironov
Introduction
Synthetic bacteriochlorins
Natural bacteriochlorins and their chemical modifications
Amphiphilic and water-soluble derivatives of bacteriochlorins
Conclusion
References
meso
-Phenylporphyrins as Synthetic Models of Natural Porphyrins: Synthesis and Modification
A.S. Semeykin, S.A. Syrbu and O.I. Koifman
Introduction
Synthesis of meso(5,10,15,20)-tetrasubstituted porphyrins
meso(5,15)-Disubstituted porphyrins
Synthesis of meso(5)-Phenyl-b-octaalkylporphyrins
Reactions of introduction and modification of substituents in phenyl rings of meso-phenyl-substituted porphyrins
References
The Mechanism of Catalytic Action of the Coordination Centres of Catalase Synthetic Models T.N. Lomova, M.E. Klyueva and M.V. Klyuev
Introduction
Substituted copper(II) porphyrins as catalysts of the hydrogen peroxide disproportionation reaction
Kinetic regularities and mechanisms of peroxide decomposition reactions in the presence of acido complexes of highly substituted manganese porphyrins
Conclusion
References
Complexation of Porphyrins with Ions and Organic Molecules N.Zh. Mamardashvili, V.V. Borovkov, G.M. Mamardashvili, Y. Inoue and O.I. Koifman
Introduction
Complexation of porphyrins with ions
Complexation of porphyrins with organic molecules: the thermodynamic aspect
Complexation of porphyrins with organic molecules: the chirality aspect
Conclusion
References
Chemical Activation of Porphyrins in Coordination Core Reactions D.B. Berezin and B.D. Berezin
Introduction
Porphyrin ligands with localized and delocalized NH bonds
Reactivity of the coordination core in molecules of porphyrin ligands
Biosignificance of the phenomenon of NH activation
References
Synthesis, Structure Peculiarities and Biological Properties of Macroheterocyclic Compounds M.K. Islyaikin, E.A. Danilova, Yu.V. Romanenko, O.G. Khelevina and T.N. Lomova
Introduction
Synthesis, structure and properties of the initial compounds
ABBB-type macroheterocyclic compounds
Azolophthalocyanines
State of triazoleporphyrazines in proton-donor media
ABAB-type macroheterocyclic compounds
ABABAB-type macroheterocyclic compounds
Coordination properties
Studies of the practically valuable properties of macroheterocyclic compounds and their metal complexes
References
The Photochemical Aspect of Reactions of Flavonols with Molecular Oxygen
E.A. Venedictov
Introduction
Structure of flavonols
Spectral luminescent properties of flavonols
Photoproduction of 1O2 (1g)
1O2 Reactions
Photochemical properties of coordination compounds of quercetine
Conclusion
References
Solvation of Drugs as a Key for Understanding Partitioning and Passive Transport Exemplified by NSAIDs German L. Perlovich and Annette Bauer-Brandl
Introduction
Partitioning and diffusion
Solvation of drugs: relevance and theoretical approaches
Experimental methods to measure solvation characteristics and choice of subjects
Crystal structures of NSAIDs
Thermochemical and thermodynamic properties of NSAIDs
The difference between partitioning and distribution of NSAIDs from the thermodynamic point of view
Correlation between biopharmaceutically relevant parameters and solvation characteristics
References
Biodamage of Materials: Adhesion of Microorganisms on the Surface of Materials K.Z. Gumargalieva, I.G. Kalinina, S.A. Semenov and G.E. Zaikov
Introduction
Results and discussion
References
Controlled Release of Aseptic Drug from Poly(3-hydroxybutyrate) Films: A Combination of Diffusion and Zero-order Kinetics
R.Y. Kosenko, Y.N. Pankova, A.L. Iordanskii, A.P. Bonartsev, and G.E. Zaikov
Introduction
Experimental
Results and discussion
Conclusion
Acknowledgement
References
Transport of Water as a Structurally Sensitive Process Characterizing the Morphology of Biodegradable Polymer Systems
A.L. Iordanskii, Yu.N. Pankova, R.Yu. Kosenko, A.A. Ol’khov and G.E. Zaikov
Introduction
Experimental
Hydrophobization of poly-(3-hydroxybutyrate)
Hydrophilization of poly-(3-hydroxybutyrate)
References
A Novel Technique for Measurement of Electrospun Nanofiber M. Ziabari, V. Mottaghitalab and A.K. Haghi
Introduction
Methodology
Experimental
Results and discussion
Conclusion
References
Image Analysis of Pore Size Distribution in Electrospun Nanofiber Webs: New Trends and Developments
M. Ziabari, V. Mottaghitalab and A.K. Haghi
Introduction
Methodology
Experimental
Results and discussion
Conclusion
References
Electrospun Biodegradable and Biocompatible Natural Nanofibers: A Detailed Review
A.K. Haghi and R.K. Haghi
Introduction
Effect of systematic parameters on electrospun nanofibers
Theory and modeling
Natural fibers
Electrospinning of silk fibers
Electrospinning of cellulose and cellulose acetate
Concluding remarks
References
Nomenclature

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Author(s)

Biography

Lomova\, ; Zaikov\, Gennady