1st Edition

Comprehensive Handbook of Chemical Bond Energies




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ISBN 9780849373664
Published March 9, 2007 by CRC Press
1684 Pages 575 B/W Illustrations

USD $670.00

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Book Description

Understanding the energy it takes to build or break chemical bonds is essential for scientists and engineers in a wide range of innovative fields, including catalysis, nanomaterials, bioengineering, environmental chemistry, and space science. Reflecting the frequent additions and updates of bond dissociation energy (BDE) data throughout the literature, the Comprehensive Handbook of Chemical Bond Energies compiles the most recent experimental BDE data for more than 19,600 bonds of 102 elements.

The author organizes the data by bond type, functional group, bond order, bond degree, molecular size, and structure for ease of use. Data can also be located using the Periodic table. The book presents data for organic molecules, biochemicals, and radicals as well as clusters, ions, hydrogen- and surface-bonded species, van der Waals complexes, isotopic species, and halogen-clusters/complexes. It also introduces entirely new data for inorganics and organometallics. The final chapter summarizes the heats of formation for atoms, inorganic/organic radicals, and monoatomic ions in the gas phase.

The Comprehensive Handbook of Chemical Bond Energies offers quick access to experimental BDE data in the most inclusive, well-organized, and up-to-date collection available today.

Table of Contents

Introduction
Experimental methods for measuring BDEs
BDEs of C-H Bonds
BDEs of C-C Bonds
BDEs of C-halogen bonds
BDEs of O-X bonds
BDEs of N-X bonds
BDEs of S-, Se-, Te-, and Po-X bonds
BDEs of Si-, Ge-, Sn-, and Pb-X bonds
BDEs of P-, As-, Sb-, and Bi-X bonds
BDEs of H(H±)-, Li(Li±)-, Na(Na±)-, K(K±)-, Rb(Rb±)-, and Cs(Cs±)-X bonds
BDEs of Be(Be+)-, Mg(Mg+)-, Ca(Ca+)-, Sr(Sr+)-, Ba(Ba+)-, and Ra-X bonds
BDEs of Sc(Sc+)-, Y(Y+)-, La(La+)-, and Ac(Ac+)-X bonds
BDEs of Ti(Ti±)-, Zr(Zr+)-, and Hf(Hf+)-X bonds
BDEs of V(V±)-, Nb(Nb+)-, and Ta(Ta+)-X bonds
BDEs of Cr(Cr±)-, Mo(Mo±)-, and W(W±)-X bonds
BDEs of Mn(Mn±)-, Tc-, and Re(Re+)-X bonds
BDEs of Fe(Fe±)-, Ru(Ru+)-, and Os(Os+)-X bonds
BDEs of Co(Co±)-, Rh(Rh+)-, and Ir(Ir+)-X bonds
BDEs of Ni(Ni±)-, Pd(Pd±)-, and Pt(Pt±)-X bonds
BDEs of Cu(Cu±)-, Ag(Ag±)-, and Au(Au±)-X bonds
BDEs of Zn(Zn+)-, Cd(Cd+)-, and Hg(Hg+)-X bonds
BDEs of B(B±)-, Al(Al±)-, Ga(Ga±)-, In(In±)-, and Tl(Tl±)-X Bonds
BDEs in the C-, Si-, Ge-, Sn-, Pb-clusters and complexes
BDEs in the N-, P-, As-, Sb-, Bi-clusters and complexes
BDEs in the O-, S-, -Se, and Te-clusters and complexes
BDEs in the halogenated molecules, clusters, and complexes
BDEs in rare gas atom/ion clusters
Heats of formation of atoms, radicals, and ions

References (1946 through 2006)
Index of compound classes
Index of compound names

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Reviews

"This book offers quick access to experimental BDE data in the most inclusive, well-organized, and up-to-date collection available today."

– In Anticancer Research, September/ October 2007, Vol. 57, No. 5A