1st Edition

Environmentally Sustainable Catalytic Asymmetric Oxidations

By Konstantin Bryliakov Copyright 2015
162 Pages 238 B/W Illustrations
by CRC Press

164 Pages 238 B/W Illustrations
by CRC Press

162 Pages
by CRC Press

Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereoselective catalyst systems. Environmentally... Read more

Introduction
Transition Metal-Catalyzed Asymmetric Epoxidations
Manganese Systems
Iron and Ruthenium Systems
Titanium Systems
Systems Based on Other Metals
Transition Metal-Catalyzed Asymmetric Sulfoxidations
Vanadium Systems
Titanium Systems
Iron Systems
Systems Based on Other Metals
Miscellaneous Transition Metal-Catalyzed Asymmetric Oxidations
Cis-Dihydroxylations of Olefins
Baeyer-Villiger Oxidations
Oxidative Kinetic Resolution of Secondary Alcohols and Desymmetrization of Meso-Diols
Enantioselective Aerobic Oxidative Coupling of 2-Naphthols
Enantioselective C-H Oxidations
Organocatalytic Asymmetric Oxidations
Epoxidations
Miscellaneous Oxidations
Fe- and Mn-Based Synthetic Models of Non-Heme Oygenases: Stereospecific C-H Oxidations
Iron Systems
Manganese Systems
Active Species and Mechanisms of Non-Heme Fe- and Mn-Catalyzed Oxidations
Iron Systems
Manganese Systems
Industrial Perspective
General Remarks
Some Examples
Outlook

Biography

Konstantin P. Bryliakov was born in Yoshkar-Ola (USSR) in 1977 and graduated from Novosibirsk State University in 1999. He earned a Cand. Chem. Sci. (PhD) in chemical physics from the Institute of Chemical Kinetics and Combustion (Novosibirsk) in 2001 under the direction of Professor E. P. Talsi. In 2008, Dr. Bryliakov was awarded a Dr. Chem. Sci. in catalysis from the Boreskov Institute of Catalysis (Novosibirsk). Dr. Bryliakov is a leading research scientist at the Boreskov Institute. He has co-authored more than 90 papers, book chapters, and patents. His research interests include transition metal-catalyzed asymmetric oxidations, single-site olefin polymerizations, and mechanistic aspects of those transformations.