1st Edition

Filled Polymers Science and Industrial Applications

By Jean L. Leblanc Copyright 2010
444 Pages 230 B/W Illustrations
by CRC Press

444 Pages
by CRC Press

The idea of mixing single available materials into compounds to fulfill a set of desired properties is likely as old as mankind. Highly sophisticated polymer applications would simply be impossible without the enhancement of some of their properties through addition of fine mineral particles or synthetic or natural short fibers. Many filled polymers, either thermoplastics or vulcanizable rubbers,... Read more

Introduction

Scope of the Book

Filled Polymers vs. Polymer Nanocomposites

 

Types of Fillers

 

Concept of Reinforcement

 

Typical Fillers for Polymers

Carbon Black

White Fillers

Short Synthetic Fibers

Short Fibers of Natural Origin

Appendix

Carbon Black Data

Medalia’s Floc Simulation for Carbon Black Aggregate

Medalia’s Aggregate Morphology Approach

Carbon Black: Number of Particles/Aggregate

 

Polymers and Carbon Black

Elastomers and Carbon Black (CB)

Thermoplastics and Carbon Black

Appendix

Network Junction Theory

Kraus Deagglomeration–Reagglomeration Model for Dynamic Strain Softening (DSS)

Ulmer Modification of the Kraus Model for Dynamic Strain Softening (DSS): Fitting the Model

Aggregates Flocculation/Entanglement

Model (Cluster–Cluster Aggregation (CCA) Model, Klüppel et al.)

Lion et al. Model for Dynamic Strain Softening (DSS)

Maier and Göritz Model for Dynamic Strain Softening (DSS)

 

Polymers and White Fillers

Elastomers and White Fillers

Thermoplastics and White Fillers

Appendix

Adsorption Kinetics of Silica on Silicone Polymers

Modeling the Shear Viscosity Function of Filled

Polymer Systems

Models for the Rheology of Suspensions of Rigid Particles,

Involving the Maximum Packing Fraction Φm

Assessing the Capabilities of Model for the Shear

Viscosity Function of Filled Polymers

Expanding the Krieger–Dougherty Relationship

 

Polymers and Short Fibers

Generalities

Micromechanic Models for Short Fibers-Filled Polymer

Composites

Thermoplastics and Short Glass Fibers

Typical Rheological Aspect of Short Fiber-Filled

Thermoplastic Melts

Thermoplastics and Short Fibers of Natural Origin

Elastomers and Short Fibers

Appendix

Short Fiber-Reinforced Composites: Minimum Fiber Aspect Ratio

Halpin–Tsai Equations for Short Fibers Filled Systems: Numerical Illustration

Nielsen Modification of Halpin–Tsai Equations with Respect to the Maximum Packing Fraction: Numerical Illustration

Mori–Tanaka’s Average Stress Concept: Tandon–Weng

Expressions for Randomly Distributed Ellipsoidal (Fiber-Like) Particles: Numerical Illustration

Shear Lag Model: Numerical illustration

 

Index

Biography

Jean L. Leblanc is the director of the Polymer Rheology and Processing Laboratory at the University P & M Curie in Paris. He has published more than 120 scientific papers and two books, contributed chapters in several collective books, made numerous presentations in international conferences, and has given seminars in Brazil, Canada, Thailand, the USA, and several European countries.