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Liquid-Liquid InterfacesTheory and Methods




ISBN 9780367448691
Published December 2, 2019 by CRC Press
448 Pages

 
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Book Description

Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area.
Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes.
Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.

Table of Contents

Equilibrium Electric Potential Between Two Immiscible Electrolyte Solutions. Distribution Potential. Polarizability of the Liquid-Liquid Interface. Nonpolarized ITIES and Reference Potentials in Organic Phases. Free Energy of Coupling of Ion Transfer and Electron Transfer. Conclusions. References.
Volta and Surface Potentials at Liquid/Liquid Interfaces. Introduction. Electrified Liquid-Liquid Interfaces and Their Electrical Potentials. Volta Potential and Voltaic Cells. Voltaic Cells with Water/Nonpolar Liquid Interfaces. Voltaic Cells with Immiscible Electrolyte Solution Interface. Experimental Methods of Investigation of Voltaic Cells. Final Remarks. References.
Ion Solvation. The Relevant Properties of Ions. The Relevant Properties of Solvents. Quantities Describing Ionic Hydration. Transfer of Ions into Non-Aqueous Solvents. Preferential Ion Solvation in Mixed Solvents. References.
Adsorption Isotherms and the Structure of Oil/Water Interface. Introduction. Surface Solution Model. Analysis of the Generalized Frumkin Isotherm. Classical Isotherms as a Special Case of the Generalized Adsorption Isotherm. Adsorption Isotherm and the Structure of Interphase. Conclusion. References.
The Electrical Double Layer at Liquid-Liquid Interfaces. Introduction. Models of Electrolytes and Double Layers. Simulations of Solvents and Interfaces. Experimental Methods. Conclusions. References.
Second Harmonic Generation at Liquid/Liquid Interfaces. Introduction. Historical Overview. Theory. Experimental Apparatus. Surface SH Origin From Neat Liquid-Liquid Interfaces. Molecular Orientation at Liquid-Liquid Interfaces. Interfacial Chemical Equilibrium. Dynamics at Liquid-Liquid Interfaces. Surface Sum-Frequency Generation. Conclusion. References.
Quantum Theory of Charge Transfer. Physical Mechanism of Charge Transfer and the Role of Polar Medium. Outer-Sphere Solvent Reorganization Energy. Electron Transfer at the Interface and Specific Forms of the Solvent Reorga

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Author(s)

Biography

Volkov, Alexander G.; Deamer, David W.