1st Edition

Nonequilibrium Processes in Catalysis

By Oleg V. Krylov Copyright 1994

    Nonequilibrium Processes in Catalysis presents modern ideas and experimental data (e.g., molecular beams, laser technique) on adsorption and catalysis, the mechanism of energy exchange in the processes of particles interaction with a surface, and the lifetimes of excited particles on a surface. Previously unpublished theoretical information regarding the principle of chemoenergetical stimulation accounting for the acceleration of one reaction at the expense of reactant excitation in another is provided, and new ideas about nonequilibrium surface diffusion are explored. Examples of the formation of nonequilibrium dissipative structures in catalysis are presented, including auto-oscillations, auto-waves, multiplicity of kinetic regimes, nonequilibrium phase transition, and decelerated electron exchange between solid and adsorbed species. The book also describes new experimental methods for studying nonequilibrium and quick processes in catalysis. Nonequilibrium Processes in Catalysis will benefit physicists involved with surface science, chemists involved with adsorption and catalysis, engineers, vacuum scientists, physical chemists, materials chemists, students, and others interested in these processes.

    Chapter 1 . Introduction Chapter 2 . Research Methods Chapter 3 . Heterogeneous Deactivation of Excited Molecules Chapter 4 Interaction . of Molecular Beams With Surface Chapter 5 . Lifetime of Excited Molecules on Surface Chapter 6 . Precursor and Nonequilibrium Diffusion Chapter 7 . Chemoenergetic Stimulation Chapter 8 . Thermodynamics of Irreversible Processes and Dissipative Structures in Catalysis Chapter 9 . Phase Transformations in Catalysis Chapter 10 . Nonequilibrium States of Catalyst


    Krylov, Oleg V.