Ozone Reaction Kinetics for Water and Wastewater Systems: 1st Edition (Hardback) book cover

Ozone Reaction Kinetics for Water and Wastewater Systems

1st Edition

By Fernando J. Beltran

CRC Press

384 pages | 107 B/W Illus.

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pub: 2003-12-29
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Description

Interest in ozonation for drinking water and wastewater treatment has soared in recent years due to ozone's potency as a disinfectant, and the increasing need to control disinfection byproducts that arise from the chlorination of water and wastewater.

Ozone Reaction Kinetics for Water and Wastewater Systems is a comprehensive reference that presents practical information to water treatment and wastewater treatment operators and researchers. It describes the application of kinetics to the effective evaluation, design, and implementation of ozone technology. This information will help plant operators determine whether or not ozone treatment is suitable for their facility, and help engineers and researchers design appropriate ozone treatment systems.

By presenting complete coverage of ozone kinetics in water and wastewater, this book provides researchers and practitioners with fundamentals of ozone kinetics as well as practical "how to" information.

Reviews

"This book is a comprehensive reference for water treatment and wastewater treatment operators and researchers … . [The information provided] will help plant operators determine whether ozone treatment is suitable for their facilities and help engineers and researchers design appropriate ozone treatment systems."

- Journal of the American Water Works Association, March 2005

Table of Contents

INTRODUCTION

Ozone in Nature

The Ozone Molecule

REACTIONS OF OZONE IN WATER

Oxidation-Reduction Reactions

Cycloaddition Reactions

Electrophilic Substitution Reactions

Necleophilic Reactions

Indirect Reactions of Ozone

KINETICS OF THE DIRECT OZONE REACTIONS

Homogenous Kinetecs

Heterogenous Kinetics

FUNDAMENTALS OF GAS-LIQUID REACTION KINETICS

Physical Absorption

Chemical Absorption

KINETIC REGIMES IN DIRECT OZONATION REACTIONS

Determination of Ozone Properties in Water

Kinetic Regimes of the Ozone Decomposition Reaction

Kinetic Regimes of Direct Ozonation Reactions

Changes of the Kinetic Regimes During Direct Ozonation Reactions

Comparison Between Absorption Theories in Ozonation Reactions

KINETCS OF THE OZONATION OF WASTEWATERS

Reactivity of Ozone in Wastewater

Critical Concentration of Wastewater

Characterization of Wastewater

Importance of pH in Wastewater Ozonation

Chemical Biological Processes

Kinetic Study of the Ozonation of Wastewaters

KINETICS OF INDIRECT REACTIONS OF OZONE IN WATER

Relative Importance of the Direct Ozone-B Reaction and the Ozone Decomposition Reaction

Relative Rates of the Oxidation of a Given Compound

Kinetic Parameters

Characterization of Natural Waters Regarding Ozone Reactivity

KINETICS OF THE OZONE/HYDROGEN PEROXIDE SYSTEM

The Kinetic Regime of the O3/H2O2 Process

Determination of Kinetic Parameters

The Ozone/Hydrogen Peroxide Oxidation of Volatile Compounds

The Competition of the Direct Reaction

KINETICS OF THE OZONE-UV RADIATION SYSTEM

Kinetics of the UV Radiation for the Removal of Contaminants from Water

Kinetics of the UV/H2O2 System

Comparison between the Kinetic Regimes of the Ozone-B and Ozone-UV Photolysis Reactions

HETEROGENEOUS CATALYTIC OZONATION

Fundamentals of Gas-Liquid-Solid Catalytic Reaction Kinetics

Kinetics of Heterogeneous Catalytic Ozone Decomposition in Water

Kinetics of Heterogeneous Catalytic Ozonation of Compounds in Water

Kinetics of Semiconductor Photocatalytic Processes

KINETIC MODELLING OF OZONE PROCESSES

Case of Slow Kinetic Regime of Ozone Absorption

Case of Fast Kinetic Regime of Ozone Absorption

Case of Intermediate or Moderate Kinetic Regime of Ozone Absorption

Time Regimes in Ozonation

Influence of the Type of Water and Gas Flows

Mathematical Models

Examples of Kinetic Modeling for Model Compounds

Kinetic Modeling of Wastewater Ozonation

Appendixes

Subject Categories

BISAC Subject Codes/Headings:
TEC010000
TECHNOLOGY & ENGINEERING / Environmental / General
TEC010030
TECHNOLOGY & ENGINEERING / Environmental / Water Supply