Solubility in Supercritical Carbon Dioxide: 1st Edition (Hardback) book cover

Solubility in Supercritical Carbon Dioxide

1st Edition

By Ram B. Gupta, Jae-Jin Shim

CRC Press

960 pages | 1237 B/W Illus.

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pub: 2006-12-06
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Description

Supercritical fluid extraction is an environmentally safe and cost-effective alternative to traditional organic solvents. Carbon dioxide is widely used as the solvent of choice for applications such as caffeine and nicotine extraction due to its mild critical temperature, nontoxicity, nonflammability, and low cost. Introducing the most complete collection of supercritical CO2 solubility data currently available, Solubility in Supercritical Carbon Dioxide features experimental data on more than 780 solutes in consistent units and an easily accessible format.

This book reflects the authors’ painstaking efforts to compile solubility data for an extensive variety of compounds including liquids, solids, polymers, foods, drugs, nutraceuticals, pesticides, dyes, and metal complexes. Each of the more than 1200 tables is arranged in alphabetical order by compound, includes a graphical plot of its data, and features the following information:

  • Compound name, molecular formula, and molecular weight
  • Temperature and pressure given in Kelvin and bar, respectively
  • Name and amount of cosolvent, if applicable
  • Molar or mass solubility, when applicable
  • Mole- or mass-fraction solubility
  • Synonyms for the compound, where available
  • Reference source for the data

Density data for CO2 appears in one appendix, while a complete list of solutes by molecular formula appears in the other. Clear, consistent, and carefully organized, Solubility in Supercritical Carbon Dioxide is the most convenient quick-lookup guide for reliable data.

Table of Contents

Abbreviations

Solubility

Molecular Weight

Nomenclature

Other

List of Solutes

Introduction

Supercritical Carbon Dioxide

Solubility in Supercritical Carbon Dioxide

Measurements of Solubility in Supercritical Carbon Dioxide

Static Methods

Dynamic Methods

Modeling of Solubility in Supercritical Carbon Dioxide

References

Solubility Data

Acenaphthene through Azobenzene

Barium bis(hexafluoroacetylacetonate) through tert-Butyl-salen

Cafestol through Cyproterone Acetate

DDT through Dotriacontane

Eflucimibe through Ewe's Milk Fat

Fenchone through Fungal Oil

Gallium tris(acetylacetonate) through Griseofulvin

Heneicosane through 1-Hydroxyxanthone

Imipramine Hydrochloride through Iron tris(2,2,7-trimethyl-3,5-octanedionate)

Jojoba Bean Oil

Ketoprofen through Krytox Picolyl Amine

Lactic Acid through Lithium Acetylacetonate

Mandelic Acid through Myristic Acid

Naphthalene through 1-Nonanol

Octacosane through Orange Peel Oil

Palladium bis(acetylacetonate) through Pyrocatechol

Quercetin through p-Quinone

Rape Seed Oil through Rosemary Oil

Salen through Syringic Acid

Taxol through Turmeric Oil

1-Undecanol through Uranyl Dinitrate—Tributyl Phosphate Complex

Vanillic Acid through Vitamin K3

Water through Wool Wax

2,5-Xylenol through D-Xylose

Yttrium tris(acetylacetonate) and Yttrium tris(hexafluoroacetylacetonate)

Zinc bis(acetylacetonate) through Zopiclone

Appendix A: Density of Carbon Dioxide

Appendix B: List of Solutes by Molecular Formula

Subject Categories

BISAC Subject Codes/Headings:
SCI013060
SCIENCE / Chemistry / Industrial & Technical