2nd Edition

Synthesis of Carbon-Phosphorus Bonds




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ISBN 9780849316173
Published December 18, 2003 by CRC Press
200 Pages - 148 B/W Illustrations

USD $280.00

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Book Description

Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus compound synthesis ñ along with the new approaches towards the preparation of compounds with aromatic and vinylic C-P bonds.

Synthesis of Carbon-Phosphorus Bonds, Second Edition serves as a useful tool in the laboratory. It offers detailed surveys of IUPAC nomenclature recommendations, common notation systems, and various experimental examples. These features help to make this text an effective source of critical and annotated references, as well as a a working guide for organic and phosphorus chemists specifically, or for any chemists working with C-P bonds.

Table of Contents

INTRODUCTION
Recent Advances in C-P Bond Formation
Nomenclature of C-P Compounds
Information Sources for C-P Compounds

SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS FROM ELEMENTAL PHOSPHORUS
Introduction
Availability of Elemental Phosphorus
Attack on Elemental Phosphorus by Nucleophiles
Radical Attack on Elemental Phosphorus
Direct Addition to P-Systems
Oxidative Additions with Olefins
Experimental Procedures
Summary
References

C-P BOND FORMATION USING NUCLEOPHILIC TRIVALENT PHOSPHORUS REAGENTS
Introduction
Substitution Reactions Using Neutral Trivalent Phosphorus Reagents
Substitution Reactions Using Anionic Trivalent Phosphorus Reagents
Preparations Of A-substituted Phosphoryl Compounds
Conjugate Addition Reactions
Experimental Procedures
References


C-P BOND FORMATION VIA DISPLACEMENT, ADDITION, OR REARRANGEMENT
Introduction
Phosphorus-halogen Compounds
Substitution Reactions on Phosphorus-halogen Compounds Using Organometallics and Related Reagents
Addition Reactions of P-H Compounds
Addition Reactions of P-Cl Compounds
Rearrangements Resulting In The Formation Of New P-C Bonds
Experimental Procedures
References

PENTACOORDINATE PHOSPHORUS
Introduction
General Structure of Pentacoordinate Phosphorus
Stable Phosphoranes
Carbonñphosphorus Bond Formation Involving
Phosphorane Intermediates
Experimental Procedures
References

AROMATIC AND VINYLIC C-P BONDS
Introduction
Aromatic Carbon-Phosphorus Bond Formation
Vinylic Carbon-Phosphorus Bond Formation
Experimental Procedures
References

Index

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Author(s)

Biography

Engel\, Robert