Synthesis of Carbon-Phosphorus Bonds: 2nd Edition (Hardback) book cover

Synthesis of Carbon-Phosphorus Bonds

2nd Edition

By Robert Engel

CRC Press

200 pages | 148 B/W Illus.

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pub: 2003-12-18
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Description

Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus compound synthesis ñ along with the new approaches towards the preparation of compounds with aromatic and vinylic C-P bonds.

Synthesis of Carbon-Phosphorus Bonds, Second Edition serves as a useful tool in the laboratory. It offers detailed surveys of IUPAC nomenclature recommendations, common notation systems, and various experimental examples. These features help to make this text an effective source of critical and annotated references, as well as a a working guide for organic and phosphorus chemists specifically, or for any chemists working with C-P bonds.

Table of Contents

INTRODUCTION

Recent Advances in C-P Bond Formation

Nomenclature of C-P Compounds

Information Sources for C-P Compounds

SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS FROM ELEMENTAL PHOSPHORUS

Introduction

Availability of Elemental Phosphorus

Attack on Elemental Phosphorus by Nucleophiles

Radical Attack on Elemental Phosphorus

Direct Addition to P-Systems

Oxidative Additions with Olefins

Experimental Procedures

Summary

References

C-P BOND FORMATION USING NUCLEOPHILIC TRIVALENT PHOSPHORUS REAGENTS

Introduction

Substitution Reactions Using Neutral Trivalent Phosphorus Reagents

Substitution Reactions Using Anionic Trivalent Phosphorus Reagents

Preparations Of A-substituted Phosphoryl Compounds

Conjugate Addition Reactions

Experimental Procedures

References

C-P BOND FORMATION VIA DISPLACEMENT, ADDITION, OR REARRANGEMENT

Introduction

Phosphorus-halogen Compounds

Substitution Reactions on Phosphorus-halogen Compounds Using Organometallics and Related Reagents

Addition Reactions of P-H Compounds

Addition Reactions of P-Cl Compounds

Rearrangements Resulting In The Formation Of New P-C Bonds

Experimental Procedures

References

PENTACOORDINATE PHOSPHORUS

Introduction

General Structure of Pentacoordinate Phosphorus

Stable Phosphoranes

Carbonñphosphorus Bond Formation Involving

Phosphorane Intermediates

Experimental Procedures

References

AROMATIC AND VINYLIC C-P BONDS

Introduction

Aromatic Carbon-Phosphorus Bond Formation

Vinylic Carbon-Phosphorus Bond Formation

Experimental Procedures

References

Index

Subject Categories

BISAC Subject Codes/Headings:
SCI013000
SCIENCE / Chemistry / General
SCI013040
SCIENCE / Chemistry / Organic
SCI013060
SCIENCE / Chemistry / Industrial & Technical