200 Pages
148 B/W Illustrations
by
CRC Press
200 Pages
by
CRC Press
Also available as eBook on:
Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus compound synthesis ñ along with the new approaches... Read more
INTRODUCTION
Recent Advances in C-P Bond Formation
Nomenclature of C-P Compounds
Information Sources for C-P Compounds
SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS FROM ELEMENTAL PHOSPHORUS
Introduction
Availability of Elemental Phosphorus
Attack on Elemental Phosphorus by Nucleophiles
Radical Attack on Elemental Phosphorus
Direct Addition to P-Systems
Oxidative Additions with Olefins
Experimental Procedures
Summary
References
C-P BOND FORMATION USING NUCLEOPHILIC TRIVALENT PHOSPHORUS REAGENTS
Introduction
Substitution Reactions Using Neutral Trivalent Phosphorus Reagents
Substitution Reactions Using Anionic Trivalent Phosphorus Reagents
Preparations Of A-substituted Phosphoryl Compounds
Conjugate Addition Reactions
Experimental Procedures
References
C-P BOND FORMATION VIA DISPLACEMENT, ADDITION, OR REARRANGEMENT
Introduction
Phosphorus-halogen Compounds
Substitution Reactions on Phosphorus-halogen Compounds Using Organometallics and Related Reagents
Addition Reactions of P-H Compounds
Addition Reactions of P-Cl Compounds
Rearrangements Resulting In The Formation Of New P-C Bonds
Experimental Procedures
References
PENTACOORDINATE PHOSPHORUS
Introduction
General Structure of Pentacoordinate Phosphorus
Stable Phosphoranes
Carbonñphosphorus Bond Formation Involving
Phosphorane Intermediates
Experimental Procedures
References
AROMATIC AND VINYLIC C-P BONDS
Introduction
Aromatic Carbon-Phosphorus Bond Formation
Vinylic Carbon-Phosphorus Bond Formation
Experimental Procedures
References
Index
Recent Advances in C-P Bond Formation
Nomenclature of C-P Compounds
Information Sources for C-P Compounds
SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS FROM ELEMENTAL PHOSPHORUS
Introduction
Availability of Elemental Phosphorus
Attack on Elemental Phosphorus by Nucleophiles
Radical Attack on Elemental Phosphorus
Direct Addition to P-Systems
Oxidative Additions with Olefins
Experimental Procedures
Summary
References
C-P BOND FORMATION USING NUCLEOPHILIC TRIVALENT PHOSPHORUS REAGENTS
Introduction
Substitution Reactions Using Neutral Trivalent Phosphorus Reagents
Substitution Reactions Using Anionic Trivalent Phosphorus Reagents
Preparations Of A-substituted Phosphoryl Compounds
Conjugate Addition Reactions
Experimental Procedures
References
C-P BOND FORMATION VIA DISPLACEMENT, ADDITION, OR REARRANGEMENT
Introduction
Phosphorus-halogen Compounds
Substitution Reactions on Phosphorus-halogen Compounds Using Organometallics and Related Reagents
Addition Reactions of P-H Compounds
Addition Reactions of P-Cl Compounds
Rearrangements Resulting In The Formation Of New P-C Bonds
Experimental Procedures
References
PENTACOORDINATE PHOSPHORUS
Introduction
General Structure of Pentacoordinate Phosphorus
Stable Phosphoranes
Carbonñphosphorus Bond Formation Involving
Phosphorane Intermediates
Experimental Procedures
References
AROMATIC AND VINYLIC C-P BONDS
Introduction
Aromatic Carbon-Phosphorus Bond Formation
Vinylic Carbon-Phosphorus Bond Formation
Experimental Procedures
References
Index
Biography
Engel\, Robert
