1st Edition

The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers

450 Pages
by CRC Press

450 Pages
by CRC Press

The monograph is intended for elucidation of the novel trend in chemical physics regarding the polymer non-crystalline phase. It stresses the physical phenomena affecting the kinetics and mechanism of chemical reactions proceeding in the non-crystalline polymer matrix (NCPM). NCPM is depicted in terms of a supramolecular (carcass-micellar) model. The model is thought to reflect heterophase packing... Read more
PREFACE CHAPTER I. INTRODUCTION. THE PROBLEM OF STRUCTURAL-PHYSICAL ORGANIZATION OF POLYMERIC NON-CRYSTALLINE PHASE CHAPTER2. STRUCTURAL MODEL OF NON-CRYSTALLINE POLYMERIC MATRIX CHAPTER 3. SUPRAMOLECULAR ASPECTS OF NCPM CHEMICAL PHYSICS CHAPTER 4. KINETIC PROBING OF NCPM GLASSY-LIKE POLYMERS WITH THE HELP OF DIBENZOYL PEROXIDE CHAPTER 5. KINETIC MODEL OF DIBENZOYL PEROXIDE CHAIN REACTION WITH STERICALLY HINDERED PHENOLS CHAPTER 6. DIBENWYL PEROXIDE KINETIC PROBING OF MELT AND RUBBERY POLYMERS CHAPTER 7. THE EXAMPLES OF HETERO-NANOPHASE KINETIC DESCRIPTION OF PHOTOCHEMICAL REACTIONS

Biography

Yuri Arsenovich Mikheev, Gennady Zaikov, N.M Emanuel Institute of Biochemical Physics, Moscow, Russia.