1st Edition
Surfactant Science and Technology Retrospects and Prospects
Surfactant research explores the forces responsible for surfactant assembly and the critical industrial, medical, and personal applications, including viscosity control, microelectronics, drug stabilization, drug delivery, cosmetics, enhanced oil recovery, and foods. Surfactant Science and Technology: Retrospects and Prospects, "a Festschrift in honor of Dr. Kash Mittal," provides a broad perspective with chapters contributed by leaders in the fields of surfactant-based physical, organic, and materials chemistries. Many of the authors participated in a special symposium in Melbourne, Australia, honoring Kash Mittal’s 100th edited book at the 18th Surfactants in Solution (SIS) meeting. Each chapter provides an overview of a specific research area, with discussions on past, present, and future directions.
The book is divided into six parts. Part I reviews the evolution of theoretical models for surfactant self-assembly, and introduces a model for interpreting ion-specific effects on aggregate properties. Part II focuses on interactions of surfactant solutions with solid supports; uses contact angles to understand hydrophobic/hydrophilic changes in a lipid layer; uses surface tension to understand molecular arrangements at interfaces; reviews spreading phenomena; discusses pattern formation on solid surfaces; and applies tensiometry to probe flavor components of espresso. Part III discusses novel DNA-based materials, multifunctional poly(amino acid)s–based graft polymers for drug delivery, and polymeric surfactants for stabilizing suspensions and emulsions.
Part IV introduces farm-based biosurfactants from natural products and "greener" biosurfactants from bacteria. Part V explores lyotropic liquid crystals and their applications in triggered drug release; microemulsion properties and controlled drug release; the role of hydrotopes in formulations and in enhancing solubilization in liquid crystals; the potential of ionic liquids to generate tunable and selective reaction media; and provides an overview of stimuli-responsive surfactants. Focusing on emulsions, Part VI reviews the design of emulsion properties for various commercial applications, the role of surfactants in the oil and gas industries, and surfactant mechanisms for soil removal via microemulsions and emulsification.
Part I Theory of Self-Assembly and Ion-Specific Effects
One Hundred Years of Micelles: Evolution of the Theory of Micellization
Ramanathan Nagarajan
Ionic Surfactants and Ion-Specific Effects: Adsorption, Micellization, and Thin Liquid Films
Radomir I. Slavchov, Stoyan I. Karakashev, and Ivan B. Ivanov
Part II Surfactants at Solid–Liquid Interfaces
Wettability of Solid-Supported Lipid Layers
E. Chibowski, Malgorzata Jurak, and Lucyna Holysz
Surfactant Adsorption Layers at Liquid Interfaces
R. Miller, V.B. Fainerman, V. Pradines, V.I. Kovalchuk, N.M. Kovalchuk, E.V. Aksenenko, L. Liggieri, F. Ravera, G. Loglio, A. Sharipova, Y. Vysotsky, D. Vollhardt, N. Mucic, R. Wüstneck, J. Krägel, and A. Javadi
Wetting and Spreading by Aqueous Surfactant Solutions
Natalia Ivanova and Victor M. Starov
Wetting Instabilities in Langmuir–Blodgett Film Deposition
V.I. Kovalchuk, E.K. Zholkovskiy, M.P. Bondarenko, and D. Vollhardt
Interfacial Studies of Coffee-Based Beverages: From Flavor Perception to Biofuels
Michele Ferrari, Francesca Ravera, Libero Liggieri, and Luciano Navarini
Part III Polymeric Surfactants and Polymer/Surfactant Mixtures
DNA Release from Cross-Linked DNA Gels and DNA Gel Particles
M. Carmen Morán, Diana Costa, M. Graça Miguel, and Björn Lindman
Advances in Poly(Amino Acid)s–Based Amphiphilic Graft Polymers and Their Biomedical Applications
Chan Woo Park, Hee-Man Yang, Se Rim Yoon, and Jong-Duk Kim
Polymeric Surfactants and Some of Their Applications
Tharwat Tadros
Part IV Biosurfactants
Biosurfactants
Girma Biresaw
Microbially Derived Biosurfactants: Sources, Design, and Structure-Property Relationships
P. Somasundaran, P. Patra, D.J. Albino, and I.M. Nambi
Part V Formulation and Application of Surfactant Aggregates
Triggered Drug Release Using Lyotropic Liquid Crystals as Delivery Vehicles
Dima Libster, Abraham Aserin, and Nissim Garti
Pharmaceutical Microemulsions and Drug Delivery
Maung Win, Paul Lang, Manu Vashishtha, and D.O. Shah
Hydrotropes: Structure and Function
Krister Holmberg
Surfactant Ionic Liquids: Potential Structured Reaction Media?
Paul Brown, Craig Butts, and Julian Eastoe
Stimuli-Responsive Surfactants: History and Applications
John Texter
Part VI Formulation and Application of Emulsions
Progress in Designing Emulsion Properties Over a Century: Emerging Phenomenological Guidelines from Generalized Formulation and Prospects to Transmute the Knowledge into Know-How
Jean-Louis Salager, Ana Forgiarini, and Johnny Bullón
An Overview of Surfactants in Enhanced Oil Recovery
Paulina M. Mwangi and Dandina N. Rao
Soil Removal by Surfactants during Cleaning Processes
Clarence A. Miller
Biography
Laurence (Larry) S. Romsted, Ph.D., is a chemistry professor at Rutgers, The State University of New Jersey in Piscataway. He has published 92 papers using physical organic chemistry methods to probe properties of association colloids, and he has given about 90 invited talks at international meetings and another 90 university seminars. In 1991, he published what proved to be a singularly important paper in Accounts of Chemical Research, "Ion Binding and Reactivity at Charged Aqueous Interfaces," that spread the pseudophase model for micellar catalysis to the world.