1st Edition

Metal Ions in Biological Systems Volume 22: Endor: EPR, and Electron Spin Echo for Probing Coordination Spheres

Edited By Helmut Sigel Copyright 1986
320 Pages
by CRC Press

320 Pages
by CRC Press

This volume focuses on the physical methods to probe the coordination sphere of metal ions in biological systems, which are based on para-magnetic species, namely, the electron nuclear double resonance (ENDOR), electron paramagnetic resonance (EPR), and electron spin echo (ESE) techniques.

Preface to the Series

Preface to Volume

Contributors

Contents of Other Volumes

Endor: Probing the Coordination Environment in Metalloproteins

Jürgen Hüttermann and Reinhard Kappl

Introduction

ENDOR Theory

ENDOR Instrumentation and Techniques

Survey of Results from Model Complexes and Metalloproteins

Concluding Remarks

Abbreviations

References

Identification of Oxygen Ligands in Metal-Nucleotide-Protein Complexes By Observation of the Mn(II)-170 Superhyperfine Coupling

Hans Robert Kalbitzer

Introduction

Theory

Applications

Conclusion and Outlook

Abbreviations and Definitions

References

Use of EPR Spectroscopy for Studying Solution Equilibria

Herald Gampp

Introduction

Analysis of EPR Line Intensities

Examples

Conclusions

Abbreviations and Definitions

References

Application of EPR Saturation Methods to Paramagnetic Metal Ions in Proteins

Marvin W. Makinen and Gregg B. Wells

Introduction

Relaxation Theory

Methods for Collecting Electron Spin-Lattice Relaxation Data

Microwave Power Saturation Studies of Paramagnetic Metal Ion Centers in Proteins and Small-Molecule

Complexes

Abbreviations

References

Electron Spin Echo: Applications to Biological Systems

Yuri Tsvetkov and Sergei A. Dikanov

Introduction

ESEEM Spectroscopy

Biological Applications of ESEEM

Conclusion

Abbreviations

References

Author Index

Subject Index

Biography

Helmut Sigel