NMR and Chemistry: An introduction to modern NMR spectroscopy, Fourth Edition, 4th Edition (Paperback) book cover

NMR and Chemistry

An introduction to modern NMR spectroscopy, Fourth Edition, 4th Edition

By J.W. Akitt, B. E. Mann

CRC Press

400 pages

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Description

Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain.

The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book.

Table of Contents

THE THEORY OF NUCLEAR MAGNETIZATION

The Properties of the Nucleus of an Atom

The Nucleus in a Magnetic Field

The Source of the NMR Signal

A Basic NMR Spetrometer

Questions

THE MAGNETIC FIELD AT THE NUCLEUS: NUCLEAR SCREENING THE CHEMICAL SHIFT

Effects Due to the Molecule

Isotope Effects

Effects Due to Unpaired Electrons

The Chemical Shift

Note on Sample Preparation, Standardization, and Solvent and Temperature Effects

Questions

INTERNUCLEAR SPIN-SPIN COUPLING

The Mutual Effects of Nuclear Magnets on Resonance Positions

The Appearance of Multiplets Arising form Spin-Spin Coupling

Spin-Spin Coupling Satellites

The Description of Spin Systems

Second-Order Effects

Questions

NUCLEAR MAGNETIC RELAXATION

Relaxation Processes in Assemblies of Nuclear Spins

Dipole-Dipole Relaxation

Quardrupolar Relaxation

Spin Rotation Relaxation: Detailed Molecular Motion

Chemical Shift Anisotropy Relaxation

Scalar Relaxation

Examples of 13C Relaxation Times

Questions

THE SPECTROMETER

The Magnet and Field Homogeneity

The Probe

Field-Frequency Lock

The Transmitter

The Detection System

Production of the Spectrum

Rapid Multiple Pulsing

Manipulations of Collected Data

Questions

MAKING THE SPINS DANCE

Decoupling

Composite Pulses

Refocusing Pulse

Questions

NMR SPECTRA OF EXCHANGING AND REACTING SYSTEMS

Systems at Equilibrium

Reaction Monitoring of Systems not at Equilibrium

Questions

MULTIPLE RESONANCE AND ONE-DIMENSIONAL PULSE SEQUENCES

Decoupling Difference Spectroscopy

The Nuclear Overhauser Effect

One-Dimensional Mutliphase Sequences

Exercises in Spectral Interpretation

TWO-DIMENSIONAL NMR SPECTROSCOPY

J-Resolved Two-Dimensional NMR Spectroscopy

Homonuclear COSY NMR Spectroscopy

Heteronuclear COSY NMR Spectroscopy

HOHAHA or TOCSY

Two-Dimensional INADEQUATE

Overhauser and Magnetization Transfer Based Two-Dimensional NMR Spectroscopy

Inverse Detection

Three-Dimensional NMR Spectroscopy

Questions

MAGNETIC RESONANCE IMAGING AND BIOMEDICAL NMR

Producing an Image

Whole Body Imaging

Diffusion and Flow

Chemical Shift Imaging

Biological Uses of Imaging - Imaging Microscopy

Industrial Uses of Imaging Techniques

Biomedical NMR

HIGH-RESOLUTION SOLID-STATE NMR

Magic Angle Spinning

Spin-1/2 Nuclei with Low Magnetogyric Ratios

I=1/2 Nuclei with High Magnetogyric Ratios

MAS of Quadropolar Nuclei

Some Applications

Deuterium, An Integral-Spin Nucleus

Questions

Bibliography

Answers to Questions

Index

Subject Categories

BISAC Subject Codes/Headings:
SCI013000
SCIENCE / Chemistry / General
SCI013010
SCIENCE / Chemistry / Analytic
SCI013060
SCIENCE / Chemistry / Industrial & Technical