Solid-State NMR in Materials Science: Principles and Applications, 1st Edition (Hardback) book cover

Solid-State NMR in Materials Science

Principles and Applications, 1st Edition

By Vladimir I. Bakhmutov

CRC Press

280 pages | 164 B/W Illus.

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pub: 2011-12-19
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Description

Solid-state NMR is a powerful physical method widely applied in modern fundamental and applied science, medicine, and industry. Its role is particularly valuable in materials chemistry due to the capability of solid-state NMR to rapidly solve tasks connected with structural descriptions of complex systems on macro and/or molecular levels, and the identification of the dynamics often responsible for complex systems mechanical properties.

Written for non-specialists, Solid-State NMR in Materials Science: Principles and Applications introduces the general physical principles of pulsed NMR, by including elements of the theory and practice in the registration of NMR signals, and by explaining different NMR equipment.

After the preliminaries, the book covers:

  • The theory and features of solid-state NMR and nuclear relaxation in solids, including dynamics of materials
  • Different materials, diamagnetic and paramagnetic, from metals and metal clusters to amorphous composites
  • The methodology of collection and interpretations of solid-state NMR data, including strategies and criteria for structural characterizations of different materials
  • Practical examples of multinuclear NMR and relaxation experiments as well as interpretations of data obtained
  • Numerous solid-state NMR experiments performed for various materials to evaluate their structure and dynamics

Written in clear and simple language, this book includes clear illustrations, numerous examples, and detailed bibliographies. It an excellent reference not only for young and experienced researchers, but also for students interested in a future in materials science.

Table of Contents

General Principles of Pulsed NMR and NMR Techniques

Early History of NMR in the Solid State

Nuclei in the External Magnetic Field

Effects of Radio Frequency Pulses

From Macroscopic Magnetization to Nuclear Relaxation and Shapes of NMR Signals

Parameters Characterizing Nuclei in the External Magnetic Field

Introducing NMR Equipment and NMR Experiments

Main Principles of Two-Dimensional NMR

Enhancement of Sensitivity in NMR

On Amorphous Materials as Potential Objects in Solid-State NMR Studies: Common and Key Problems

Hybrid Materials

Polymer Solids

Systems Based on Nanostructures

Wood and Wood Components

Glasses

Zeolites

Design of Porous and Layered Molecular Systems

Features of Solid-State NMR: Diamagnetic Materials

From Isotropic Chemical Shifts to Magnetic Shielding Tensors

Nuclei with a Spin of 1/2

Quadrupolar Nuclei in Solids

Detection of NMR Signals in Solids: Common Aspects

High-Power Decoupling

Multi-Quantum NMR Experiments

Dipolar Recoupling NMR Techniques

Sideband Manipulations

Zero-Field Solid-State NMR Experiments

Solid-State NMR Imaging

Practice of Multinuclear NMR in Diamagnetic Solids: General Information and Examples of Applications

Structural Information by Increasing the Spectral Resolution in Multinuclear Solid-State NMR

Probing Proximities of Nuclei and Measurements of Internuclear Distances in Diamagnetic Solids

31P Solid-State NMR

Solid-State NMR of Halogen Nuclei and Oxygen

Solid-State NMR of Oxide Materials: Nuclei 51V, 93Nb, and 181Ta

Solid-State 13C NMR: Wood and Wood Products

2H NMR in Solids at Deuterium Natural Abundance

Between Solution- and Solid-State NMR: Nanoparticles and Suspensions

Dynamics in Diamagnetic Materials from Solid-State NMR: Methods, Measurements, and Analysis

Variable-Temperature Solid-State NMR Experiments and a Line-Shape Analysis

Molecular Mobility from the Solid-State NMR Relaxation

One- and Two-Dimensional Exchange Solid-State NMR Spectroscopy

Molecular Mobility from the Cross-Polarization NMR Experiments

Molecular Mobility from Magnetic Relaxation Dispersion Experiments

Strategies in Solid-State Multinuclear NMR: Studies of Diamagnetic Porous Materials

Porosity of Materials from NMR

Structural Features of Silica Lattice and Surface by Solid-State 1H 29Si, 27Al, and 17O NMR Spectra

Molecular Mobility in Diamagnetic Porous Materials

Paramagnetic Effects in Solid-State NMR

Theoretical Aspects

Nuclear Relaxation in the Presence of Unpaired Electrons

Practical Consequences from the Theory of Paramagnetic Effects

1H, 31P, 13C, 2H, 29Si, 7Li, and 6Li NMR Spectra of Paramagnetic Solids

51V and 55Mn NMR Spectra of Paramagnetic Solids

Special NMR Techniques for Observations of "Invisible" Target Nuclei

Relaxation Measurements and Relaxation Times in Paramagnetic Solids

Strategy in NMR Studies of Amorphous Porous Paramagnetic Materials

Intense Sideband Patterns in MAS NMR Spectra of Paramagnetic Amorphous Materials and Their Analysis

Direct Detection of the Nuclei Closest to Paramagnetic Ions in Porous Materials by the Hahn-Echo Mapping NMR Experiments

NMR Relaxation Approaches to Structure of Porous Amorphous Paramagnetic Silica-Based Materials: From Experiments to Models and Interpretations

Protocol for Quantification of "Invisible Nuclei" in MAS NMR

Concluding Remarks

About the Author

Vladimir I. Bakhmutov is currently an NMR expert at Texas A&M University and a Blinn College Faculty member.

Subject Categories

BISAC Subject Codes/Headings:
SCI077000
SCIENCE / Solid State Physics
SCI078000
SCIENCE / Spectroscopy & Spectrum Analysis
TEC021000
TECHNOLOGY & ENGINEERING / Material Science